Advertisement

Thermal Pericyclic Reaction between Alkynes and Alkanes

Authors

  • Dr. Jürgen Metzger,

    1. Fachbereich 4 (Naturwissenschaften) der Universität, Ammerländer Heerstr. 67–99, D-2900 Oldenburg (Germany)
    Search for more papers by this author
  • Prof. Dr. Peter Köll

    Corresponding author
    1. Fachbereich 4 (Naturwissenschaften) der Universität, Ammerländer Heerstr. 67–99, D-2900 Oldenburg (Germany)
    • Fachbereich 4 (Naturwissenschaften) der Universität, Ammerländer Heerstr. 67—99, D-2900 Oldenburg (Germany)
    Search for more papers by this author

  • Part 4 High-Pressure/High-Temperature Reactions in a Flow Apparatus.—Part 3: P. Köll, E. Steinweg, U. Lackmann, J. Metzger, Tetrahedron Lett., in press.

Abstract

original image

A simple “HP-HT” apparatus provides the frequently cited “suitable conditions” for many reactions which cannot(yet) be accomplished by other methods. Such processes are ene reactions between nonactivated components like (1) and (2), and pericyclic reactions between alkynes and alkanes (“ane reactions”).

Ancillary