We wish to thank Professor Dr. A. Nakamura and Dr. K. Miki of Osaka University and Professor Dr. T. Ashida and Prof. Dr. T. Sakabe of Nagoya University for useful comments.
A Metalloporphyrin Containing Carbyne-like Carbido Carbon: 5,10,15,20-Tetraphenylporphyrinato[bis(μ-carbidotricarbonylrhenium)]tin(IV)†
Article first published online: 22 DEC 2003
Copyright © 1979 by Verlag Chemie, GmbH, Germany
Angewandte Chemie International Edition in English
Volume 18, Issue 1, page 83, January 1979
How to Cite
Noda, I., Kato, S., Mizuta, M., Yasuoka, N. and Kasai, N. (1979), A Metalloporphyrin Containing Carbyne-like Carbido Carbon: 5,10,15,20-Tetraphenylporphyrinato[bis(μ-carbidotricarbonylrhenium)]tin(IV). Angew. Chem. Int. Ed. Engl., 18: 83. doi: 10.1002/anie.197900831
- Issue published online: 22 DEC 2003
- Article first published online: 22 DEC 2003
- Manuscript Received: 10 OCT 1978
In the μ-carbido complex(4), obtained as shown below, the tin atom is linked to the rhenium atoms via a carbide carbon atom which bonds like a carbyne to the rhenium (TPP stands for tetraphenylporphyrin). An impression of the spatial arrangement of the complexes of type (3), which are formed at only slightly higher temperatures than (4), is provided by the adjacent formula.