Stepwise Reaction of Phenylbis(trimethylsilyl)phosphane with Phosgene—Isolation of a (Phosphinomethylene)phosphane

Authors

  • Prof. Dr. Rolf Appel,

    Corresponding author
    1. Anorganisch-chemisches Institut der Universität, Gerhard-Domagk-Strasse 1, D-5300 Bonn 1 (Germany)
    • Anorganisch-chemisches Institut der Universität, Gerhard-Domagk-Strasse 1, D-5300 Bonn 1 (Germany)
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  • Dipl.-Chem. Volker Barth

    1. Anorganisch-chemisches Institut der Universität, Gerhard-Domagk-Strasse 1, D-5300 Bonn 1 (Germany)
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  • Phosphorus-Carbon-Halogen Compounds, Part 17.–Part 16: R. Appel, M. Huppertz, Z. Anorg. Allg. Chem., in press.

Abstract

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Three intermediates of chlorination of PhP(SiMe3)2 with phosgene have been isolated and some of them characterized. The open-chain compound (2) having a P[DOUBLE BOND]C bond deserves special mention.

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