Reactions of Cycloalkeno-1,2,3-selenadiazoles with Transition Metal Carbonyls

Authors

  • Prof. Dr. Keith H. Pannell,

    Corresponding author
    1. Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968 (USA)
    • Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968 (USA)
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  • Dr. Armin J. Mayr,

    1. Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968 (USA)
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  • Rodney Hoggard,

    1. Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968 (USA)
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  • Prof. Dr. Roger C. Pettersen

    Corresponding author
    1. Department of Chemistry, Texas A. & M. University, College Station, Texas 77483 (USA)
    • Department of Chemistry, Texas A. & M. University, College Station, Texas 77483 (USA)
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  • Organometallic Heterccyclic Reactions, Part 4. Support of this research by the Robert A. Welch Foundation, Houston, Texas, and the N.I.H. Institute of Arthritis, Metabolism, and Digestive Diseases (S06 RR-08012-09) is gratefully acknowledged.—Part 3: K. H. Pannell, Ramon Iglesias, Inorg. Chim. Acta 33, L 161 (1979).

Abstract

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Complexes of a new type, the cage compounds (1), n = 4, 5, 6, are formed at room temperature from annelated selenadiazoles with Fe2(CO)9. On heating, the complexes (1) are transformed into known complexes with two Fe(CO)3 ligands.

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