This work was support by the Deutsche Forschungsgemeinschaft.
Permethylated Electron-Excess Metallocenes†
Article first published online: 22 DEC 2003
Copyright © 1980 by Verlag Chemie, GmbH, Germany
Angewandte Chemie International Edition in English
Volume 19, Issue 8, pages 640–641, August 1980
How to Cite
Koelle, U. and Khouzami, F. (1980), Permethylated Electron-Excess Metallocenes. Angew. Chem. Int. Ed. Engl., 19: 640–641. doi: 10.1002/anie.198006401
- Issue published online: 22 DEC 2003
- Article first published online: 22 DEC 2003
- Manuscript Revised: 22 APR 1980
- Manuscript Received: 18 JAN 1980
The new compounds permethylcobaltocene and -nickelocene show some surprising reactions which are impossible in the case of the parent compounds. For example, as the first neutral 20-electron complex, permethyl-nick-elocene adds electrophiles R′X to form the novel salts (1), which are stable to air and water.