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The first cyclotriphosphazenes with P-coordinated metal (2) are formed on treatment of (1) with PdCl2 or K2PtCl4via a 1,2-H shift. X-ray structure analysis was performed in the case of (2), M = Pd, X = Cl. In the other metalated cyclotriphosphazenes the metal (Li, Cu1) is N-coordinated.