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A Novel SN-Ligand: Structure of PtCl(S4N3)

Authors

  • Dr. Helmut Endres,

    1. Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (Germany)
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  • Dipl.-Chem. Elisabeth Galantai

    Corresponding author
    1. Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (Germany)
    • Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (Germany)
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Abstract

S4Nmath image, a new tridentate ligand with alternating S and N atoms has been obtained from S4N4. The reaction of S4N4 with cis-tCl2(NCPh)2 leads to deep purple PtCl(S4N3) in which the terminal S atoms and the central N atom of the ligand are coordinated to the Pt atom.

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