Cleavage of the Metal-Metal Triple Bond by Chelate-Forming Diazoalkane Bridges

Authors

  • Prof. Dr. Wolfgang A. Herrmann,

    Corresponding author
    1. Institut für Anorganische Chemie der Universität, Niederurseler Hang, D-6000 Frankfurt am Main 50 (Germany)
    • Institut für Anorganische Chemie der Universität, Niederurseler Hang, D-6000 Frankfurt am Main 50 (Germany)
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  • Gangolf W. Kriechbaum,

    1. Institut für Anorganische Chemie der Universität, Niederurseler Hang, D-6000 Frankfurt am Main 50 (Germany)
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  • Prof. Dr. Manfred Ziegler,

    1. Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (Germany)
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  • Heike Pfisterer

    1. Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (Germany)
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  • Note added in proof (August 12, 1982): A conventional methylene bridge is present in the complex of composition (η5-C5Me5)2Mo2(CO)4(μ-CH2)(μ-CH2N2) synthesized from 4 and CH2N2 (L. K. Bell, W. A. Herrmann, unpublished results 1982).

  • Dedicated to Professor Klaus Weissermel on the occasion of his 60th birthday

Abstract

The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1982, 1575. DOI:10.1002/anie.198215750

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