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[Cp2Ti(PMe3)2]—A Versatile Source of Titanocene Derivatives

Authors

  • Lawrence B. Kool,

    1. Department of Chemistry, University of Massachusetts, Amherst, MA 01003 (USA)
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  • Prof. Dr. Marvin D. Rausch,

    Corresponding author
    1. Department of Chemistry, University of Massachusetts, Amherst, MA 01003 (USA)
    • Department of Chemistry, University of Massachusetts, Amherst, MA 01003 (USA)
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  • Priv.-Doz. Dr. Helmut G. Alt,

    Corresponding author
    1. Laboratorium für Anorganische Chemie der Universität, Universitätsstrasse 30, D-8580 Bayreuth (FRG)
    • Laboratorium für Anorganische Chemie der Universität, Universitätsstrasse 30, D-8580 Bayreuth (FRG)
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  • Prof. Dr. Max Herberhold,

    1. Laboratorium für Anorganische Chemie der Universität, Universitätsstrasse 30, D-8580 Bayreuth (FRG)
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  • Prof. Dr. Ulf Thewalt,

    1. Sektion für Röntgen- und Elektronenbeugung der Universität, Oberer Eselsberg, D-7900 Ulm (FRG)
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    • X-ray structure analysis.

  • Brigitte Wolf

    1. Sektion für Röntgen- und Elektronenbeugung der Universität, Oberer Eselsberg, D-7900 Ulm (FRG)
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  • This work was supported by the National Science Foundation (USA), the Deutsche Forschungsgemeinschaft, and the Fonds der Chemischen Industrie. M. D. R. thanks the Alexander-von-Humboldt-Stiftung for the award of a Humboldt Prize (Senior U.S. Scientist Award).

Abstract

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The title compound 1 can be viewed as trimethylphosphane-substituted titanocene. 1 provides a readily accessible and simple source of titanocene in solution; the PMe3 ligands can be replaced by a variety of substrates under mild conditions.

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