Lower coordinated phosphorus compounds, Part 38.—Part 37: R. Appel, J. Menzel, F. Knoch, Chem. Ber., in press.
Article first published online: 22 DEC 2003
Copyright © 1985 by VCH Verlagsgesellschaft mbH, Germany
Angewandte Chemie International Edition in English
Volume 24, Issue 5, pages 420–421, May 1985
How to Cite
Appel, R., Schuhn, W. and Knoch, F. (1985), Tricarbonyl(1,3-diphosphaallyl)cobalt, a Phosphorus Analogue of (η3-Allyl)tricarbonylcobalt. Angew. Chem. Int. Ed. Engl., 24: 420–421. doi: 10.1002/anie.198504201
Dedicated to Professor Günther Wilke on the occasion of his 60th birthday
- Issue published online: 22 DEC 2003
- Article first published online: 22 DEC 2003
- Manuscript Revised: 4 MAR 1985
- Manuscript Received: 30 JAN 1985
The first η31,3-diphosphaallyl complex 3 could be obtained from the methylenephosphane 1 and sodium tetracarbonylcobaltate 2. In 3, whose structure has been elucidated by an X-ray structure analysis, the PC distances are identical and lie between those of a PC single and a PC double bond (R = 2,4,6-tri-tert-butylphenyl).