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By extraction of tertiary K[BOND]Au[BOND]Te alloys, the salts 13, which contain new KAuTe polyanions, could be obtained. The anion of 1 can be roughly described as a derivative of an [M12X8]4⊖ cube; in 2 and 3, planar [Au4Te4]4⊖ rings are present, the sides of which are capped by K.

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