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Crystalline Cd(SPh)2 is math image{(μ-SPh)6Cd4(μ-SPh)4/2}, an inorganic polymer. It consists of Cd4(SPh)6 cages having adamantane-like structure, each of which is linked with four surrounding cages by four SPh bridges. The three-dimen-113Cd-NMR spectrum indicates that the polymer forms Cd10(SPh)20 molecules having tetraadamantanoid structure upon solution in dimethylformamide.