1H NMR spectroscopy.
Organobimetallic MgPd Complexes as Intermediates in the Formation of Amorphous MgPdCxHy from Mg(C2H5)2 and [Pd(η3-C3H5)2]†
Article first published online: 22 DEC 2003
Copyright © 1988 by VCH Verlagsgesellschaft mbH, Germany
Angewandte Chemie International Edition in English
Volume 27, Issue 11, pages 1513–1516, November 1988
How to Cite
Bogdanović, B., Huckett, S. C., Wilczok, U. and Rufiǹska, A. (1988), Organobimetallic MgPd Complexes as Intermediates in the Formation of Amorphous MgPdCxHy from Mg(C2H5)2 and [Pd(η3-C3H5)2]. Angew. Chem. Int. Ed. Engl., 27: 1513–1516. doi: 10.1002/anie.198815131
This work was supported by the North Atlantic Treaty Organization under a Grant awarded to S. C. H. (1987). We gratefully acknowledge Dr. R. Mynott, B. Gabor, and S. Zöcklein for obtaining and interpreting the 13C NMR data, as well as R, Ettl and G. Schroth for their contributions in obtaining and analyzing the 1H NMR data.
- Issue published online: 22 DEC 2003
- Article first published online: 22 DEC 2003
- Manuscript Revised: 8 AUG 1988
- Manuscript Received: 24 MAY 1988
1 and 2 were identified by NMR spectroscopy at low temperature as intermediates in the formation of amorphous MgPdCxHy3 from Mg(C2H5)2 and [Pd(η3-C3H5)2]. The experimentally determined product ratio 3: ethene:propene:ethane = 1:2:1:1 can be explained on the basis of the formation of a further intermediate from 2 and Mg(C2H5)2. 3 is of interest as an organometallic precursor for the deposition of intermetallic compounds from the gas phase.