Organobimetallic Mg[BOND]Pd Complexes as Intermediates in the Formation of Amorphous MgPdCxHy from Mg(C2H5)2 and [Pd(η3-C3H5)2]

Authors

  • Prof. Dr. Borislav Bogdanović,

    Corresponding author
    1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a. d. Ruhr (FRG)
    • Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a. d. Ruhr (FRG)
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  • Dr. Sara C. Huckett,

    1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a. d. Ruhr (FRG)
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  • Ursula Wilczok,

    1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a. d. Ruhr (FRG)
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  • Dr. Anna Rufiǹska

    1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a. d. Ruhr (FRG)
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    • 1H NMR spectroscopy.


  • This work was supported by the North Atlantic Treaty Organization under a Grant awarded to S. C. H. (1987). We gratefully acknowledge Dr. R. Mynott, B. Gabor, and S. Zöcklein for obtaining and interpreting the 13C NMR data, as well as R, Ettl and G. Schroth for their contributions in obtaining and analyzing the 1H NMR data.

Abstract

original image

1 and 2 were identified by NMR spectroscopy at low temperature as intermediates in the formation of amorphous MgPdCxHy3 from Mg(C2H5)2 and [Pd(η3-C3H5)2]. The experimentally determined product ratio 3: ethene:propene:ethane = 1:2:1:1 can be explained on the basis of the formation of a further intermediate from 2 and Mg(C2H5)2. 3 is of interest as an organometallic precursor for the deposition of intermetallic compounds from the gas phase.

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