1,3,5-Trithia-2,4,6-triazapentalenyl — a Stable Sulfur-Nitrogen Radical

Authors

  • Dr. Gotthelf Wolmershäuser,

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    1. Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)
    • Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)
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  • Dipl.-Chem. Rudolf Johann

    1. Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)
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  • This work was supported by the Deutsche forschungsgemeinschaft.

Abstract

original image

The title compound is of interest as a likely candidate for the synthesis of conductive systems, l, a persistent radical which is arranged in stacks in the solid state, was obtained in a multistep synthesis. Between the stacks there are weak S … S interactions, whereas within the stack there is no mentionable interaction.

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