Catalytic Reactions of Metalloporphyrins, Part 5. This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, and Culture of Japan. —Part 4: Y. Aoyama, K. Midorikawa, H. Toi, H. Ogoshi, Chem. Lett. 1987, 1651.
Amide Bond Scission via Bifunctional Activation with Bimetallic Porphyrin Systems with Two Different Metal Centers†
Article first published online: 30 DEC 2003
Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany
Angewandte Chemie International Edition in English
Volume 28, Issue 7, pages 921–922, July 1989
How to Cite
Aoyama, Y., Motomura, T. and Ogoshi, H. (1989), Amide Bond Scission via Bifunctional Activation with Bimetallic Porphyrin Systems with Two Different Metal Centers. Angew. Chem. Int. Ed. Engl., 28: 921–922. doi: 10.1002/anie.198909211
- Issue published online: 30 DEC 2003
- Article first published online: 30 DEC 2003
- Manuscript Received: 6 FEB 1989
Multicenter interactions play an important role in biomimetic catalysts and receptors. It has now been possible to develop a RhIIIAgI system which accelerates the methanolysis of p-nitroacetanilide (stoichiometrically) and the transesterification of ethyl acetate with methanol (catalytically). 1 shows the double activation in the intermediary adduct.