Amide Bond Scission via Bifunctional Activation with Bimetallic Porphyrin Systems with Two Different Metal Centers

Authors

  • Prof. Dr. Yasuhiro Aoyama,

    Corresponding author
    1. Department of Chemistry, Nagaoka University of Technology, Kamitomioka, Nagaoka, Niigata 940-21 (Japan)
    • Department of Chemistry, Nagaoka University of Technology, Kamitomioka, Nagaoka, Niigata 940-21 (Japan)
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  • Tadahiro Motomura,

    1. Department of Chemistry, Nagaoka University of Technology, Kamitomioka, Nagaoka, Niigata 940-21 (Japan)
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  • Prof. Dr. Hisanobu Ogoshi

    Corresponding author
    1. Department of Synthetic Chemistry, Kyoto University, Saklyo-Ku, Kyoto 606 (Japan)
    • Department of Synthetic Chemistry, Kyoto University, Saklyo-Ku, Kyoto 606 (Japan)
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  • Catalytic Reactions of Metalloporphyrins, Part 5. This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, and Culture of Japan. —Part 4: Y. Aoyama, K. Midorikawa, H. Toi, H. Ogoshi, Chem. Lett. 1987, 1651.

Abstract

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Multicenter interactions play an important role in biomimetic catalysts and receptors. It has now been possible to develop a RhIIIAgI system which accelerates the methanolysis of p-nitroacetanilide (stoichiometrically) and the transesterification of ethyl acetate with methanol (catalytically). 1 shows the double activation in the intermediary adduct.

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