Sulfur Compounds, Part 128. This work was supported by the Deutsche Forschungsgemeinschaft and the Verband der Chemischen Industrie. Part 127:R. Steudel, G. Holdt, T. Göbel, J. Chromatogr. 475 (1989) 442.
Synthesis and Structure of [(C5H5)2TiS4AsCH3]—a New Reagent for the Synthesis of Sulfur-Rich Heterocycles†
Article first published online: 30 DEC 2003
Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany
Angewandte Chemie International Edition in English
Volume 28, Issue 9, pages 1269–1271, September 1989
How to Cite
Steudel, R., Holz, B. and Pickardt, J. (1989), Synthesis and Structure of [(C5H5)2TiS4AsCH3]—a New Reagent for the Synthesis of Sulfur-Rich Heterocycles. Angew. Chem. Int. Ed. Engl., 28: 1269–1271. doi: 10.1002/anie.198912691
- Issue published online: 30 DEC 2003
- Article first published online: 30 DEC 2003
- Manuscript Received: 28 APR 1989
The cleavage of binuclear titanocene polysulfide complexes [reaction (a)] is useful in the synthesis of the title compound 1. Reaction probably occurs in an analogous fashion with many elemental dihalides (ECl2 or RxEC12) and should therefore open the way to a wide variety of new titanocene complexes. Compound 1 contains a bimetallic heterocycle that functions as a transfer reagent for S4AsCH3.