Two Novel Polyoxomolybdates Containing the (MoNO)3⊕ Unit: [Mo5Na(NO)O13(OCH3)4]2⊖ and [Mo6(NO)O18]3⊖

Authors

  • Dr. Pierre Gouzerh,

    Corresponding author
    1. Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05 (France)
    • Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05 (France)
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  • Prof. Dr. Yves Jeannin,

    1. Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05 (France)
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  • Anna Proust,

    1. Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05 (France)
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  • Francis Robert

    1. Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05 (France)
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  • This work was supported by the Centre National de la Recherche Scientifique under contract URA 419.

Abstract

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The first polyoxomolybdates with an MoIINO instead of an MoIV O group are compounds 2 and 3. They were obtained by reductive nitrosylation of complex 1 with hydroxylamine in methanol. Pentamolybdate 2 is transformed into hexamolybdate 3 upon dissolution, for example in CH2Cl2. The structures of both title compounds are derived from the Lindgvist structure [Mo6O19]2⊖.

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