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Synthesis and Structure of the Novel μ2-Carbido Complex [(TPP)Fe[DOUBLE BOND]C[DOUBLE BOND]Re(CO)4 Re(CO)5]

Authors

  • Prof. Dr. Wolfgang Beck,

    Corresponding author
    1. Institut für Anorganische Chemie der Universität Meiserstr. 1, D-8000 München (FRG)
    • Institut für Anorganische Chemie der Universität Meiserstr. 1, D-8000 München (FRG)
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  • Dipl.-Chem. Wolfgang Knauer,

    1. Institut für Anorganische Chemie der Universität Meiserstr. 1, D-8000 München (FRG)
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  • Dr. habil. Christian Robl

    1. Institut für Anorganische Chemie der Universität Meiserstr. 1, D-8000 München (FRG)
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    • X-ray structure analysis.


  • Hydrocarbon-Bridged Complexes, Part 16. This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. We thank Professor Dr. W. Herrmann and Dr. E. Herdtweck, Technische Universität München, for valuable discussions.—Part 15:[18].

  • Dedicated to Professor Günther Wilke on the occasion of his 60th birthday

Abstract

The title compound 2 contains an Fe[DOUBLE BOND]C[BOND]Re[BOND]Re unit. This 1,3-dimetallaallene is a novel example of the rare carbide-bridged complexes. 2 is formed on reaction of the dichlorocarbene complex 1 with pentacarbonylrhenate (TPP [DOUBLE BOND] tetra-phenylporphyrinate).

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