SEARCH

SEARCH BY CITATION

Thumbnail image of graphical abstract

Six η1-O-coordinated SO2 ligands are present in the pinwheel-shaped cation of complex 1. This mode of coordination was considered unusual. The synthesis was achieved by oxidation of Ni powder with AsF5 in liquid SO2. An analogous reaction with iron yielded m-[Fe(SO2)4(FAsF5)2].

  • equation image