This work was supported by the Deutsche Forschungsgemeinschaft (SFB 301).
Synthesis and Characterization of the First Thiaselanes†
Article first published online: 22 DEC 2003
Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
Angewandte Chemie International Edition in English
Volume 33, Issue 17, pages 1770–1772, September 16, 1994
How to Cite
Hahn, J. and Klünsch, R. (1994), Synthesis and Characterization of the First Thiaselanes. Angew. Chem. Int. Ed. Engl., 33: 1770–1772. doi: 10.1002/anie.199417701
- Issue published online: 22 DEC 2003
- Article first published online: 22 DEC 2003
- Manuscript Received: 18 MAR 1994
Stable as a solid at −40°C, dithiatriselane 1 was formed in the reaction of Se2Cl2 with liquid H2S in CS2, in addition to other disproportionation products such as 2 and 3. Reactions in H2S2 provided sulfur-rich thiaselanes. The 1H and 77Se NMR spectra of the product mixtures could be interpreted unambiguously.