Porphyrin–Quinone Cyclophanes with Gradually Varied Donor–Acceptor Distances

Authors

  • Prof. Dr. Heinz A. Staab,

    Corresponding author
    1. Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung, Jahnstrasse 29, D-69120 Heidelberg (FRG) Telefax: Int. code + (6221)486-219
    • Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung Jahnstrasse 29, D-69120 Heidelberg (FRG) Telefax: Int. code + (6221)486-219
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  • Dr. Ralf Hauck,

    1. Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung, Jahnstrasse 29, D-69120 Heidelberg (FRG) Telefax: Int. code + (6221)486-219
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  • Dr. Achim Feurer

    1. Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung, Jahnstrasse 29, D-69120 Heidelberg (FRG) Telefax: Int. code + (6221)486-219
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  • Photoinduced Electron Transfer in Porphyrin–Quinone Cyclophanes, Part 13. Part 12: [4b].

Abstract

original image

How does the rate of electron transfer between the quinone and porphyrin units in cyclophanes of type 1 vary with distance? H. A. Staab et al. report here on the synthesis and properties of cyclophanes with benzene, naphthalene (1), and anthracene spacers, which were examined by spectroscopy, X-ray structure analysis, and molecular dynamics calculations.

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