Almost rectangular cavities can be seen in the structure of the title compound (part of the crystal structure shown on the right), the first heteropolyoxo-tungstate with defined micropores. The compound was prepared in a hydrothermal reaction with W, WO3, H3PO4, H2O, and hexamethylenediamine. Potential applications of this compound in catalytic oxidations or as a support in shape-selective reactions must still be proven.
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