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Keywords:

  • magnetic properties;
  • manganese compounds;
  • Prussian blue;
  • salen complexes
Thumbnail image of graphical abstract

Cyclic tetrameric units (··Mn-NC-Fe-CN··)4 (depicted on the right) construct the two-dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.