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Keywords:

  • cyclopentadienyl complexes;
  • macrocycles;
  • pseudopeptides;
  • titanium compounds
Thumbnail image of graphical abstract

Preorganization by intramolecular hydrogen bonds facilitates the synthesis of macrobicyclic TiIV complexes with ring sizes up to 32 atoms (shown schematically below). C3-symmetric peptide bundles, each fixed by a central nitrogen atom, serve as ligands. AS [DOUBLE BOND] α-amino acids (Gly, Leu, Phe, Val).