Communication

XeOFmath image, an Anion with Pentagonal-Pyramidal Structure†

  1. Dr. Arkady Ellern,
  2. Prof. Dr. Konard Seppelt*

Article first published online: 22 DEC 2003

DOI: 10.1002/anie.199515861

Issue

Angewandte Chemie International Edition in English

Angewandte Chemie International Edition in English

Volume 34, Issue 15, pages 1586–1587, August 18, 1995

Additional Information

How to Cite

Ellern, A. and Seppelt, K. (1995), XeOFmath image, an Anion with Pentagonal-Pyramidal Structure. Angew. Chem. Int. Ed. Engl., 34: 1586–1587. doi: 10.1002/anie.199515861

Author Information

  1. Institut für Anorganische und Analytische Chemie der Freien Universität Berlin, Fabeckstrasse 34–36, D-14195 Berlin (Germany) Telefax: Int. code + (30)838-2424 e-mail: seppelt@blume.chemie.fu-berlin.de

*Institut für Anorganische und Analytische Chemie der Freien Universität Berlin, Fabeckstrasse 34–36, D-14195 Berlin (Germany) Telefax: Int. code + (30)838-2424 e-mail: seppelt@blume.chemie.fu-berlin.de

  1. †

    This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. We thank the Alexander von Humboldt Foundation for scholarship for A. E.

Publication History

  1. Issue published online: 22 DEC 2003
  2. Article first published online: 22 DEC 2003
  3. Manuscript Received: 15 MAR 1995

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Keywords:

  • fluorine compounds;
  • xenon compounds
Thumbnail image of graphical abstract

Only minimally distorted by interionic forces in the crystal, the ion XeOFmath image (picture on the right, bond lengths in pm) can be crystallized as NO+XeOFmath image. The xenon atom is situated only slightly above the plane through the fluorine atoms, and the doubly bonded oxygen atom occupies the apical position of the pentagonal pyramid. NO+XeOFmath image is formed directly by treatment of NOF with an equimolar amount of XeOF4 and crystallizes spontaneously from the liquid phase.

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