Structural Diversity in Alkali Metal Phospholides: A Kalocene-Type Structure

Authors

  • Dr. Frédéric Paul,

    1. Laboratoire “Hétéroéléments et Coordination” URA 1499 CNRS, DCPH Ecole Polytechnique, F-91128 Palaiseau Cedex (France) Fax: Int. code +(1)69333990
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  • Dr. Duncan Carmichael,

    1. Laboratoire “Hétéroéléments et Coordination” URA 1499 CNRS, DCPH Ecole Polytechnique, F-91128 Palaiseau Cedex (France) Fax: Int. code +(1)69333990
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  • Dr. Louis Ricard,

    1. Laboratoire “Hétéroéléments et Coordination” URA 1499 CNRS, DCPH Ecole Polytechnique, F-91128 Palaiseau Cedex (France) Fax: Int. code +(1)69333990
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  • Prof. Dr. François Mathey

    Corresponding author
    1. Laboratoire “Hétéroéléments et Coordination” URA 1499 CNRS, DCPH Ecole Polytechnique, F-91128 Palaiseau Cedex (France) Fax: Int. code +(1)69333990
    • Laboratoire “Hétéroéléments et Coordination” URA 1499 CNRS, DCPH Ecole Polytechnique, F-91128 Palaiseau Cedex (France) Fax: Int. code +(1)69333990
    Search for more papers by this author

Abstract

original image

Phospholide anions can stabilize unusual structures, for example the first crystallographically characterized derivative of “kalocene” (structural formula on the right). Counterion: [K([18]crown-6)(THF)2]+.

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