Communication

The Novel Encapsulation of Transition Metals in a Bioctahedral Rare Earth Metal Cluster: Cs2La10I17Co2†

  1. Dr. Michael Lulei,
  2. Paul A. Maggard,
  3. Prof. John D. Corbett*

Article first published online: 22 DEC 2003

DOI: 10.1002/anie.199617041

Issue

Angewandte Chemie International Edition in English

Angewandte Chemie International Edition in English

Volume 35, Issue 15, pages 1704–1706, August 1996

Additional Information

How to Cite

Lulei, M., Maggard, P. A. and Corbett, J. D. (1996), The Novel Encapsulation of Transition Metals in a Bioctahedral Rare Earth Metal Cluster: Cs2La10I17Co2. Angew. Chem. Int. Ed. Engl., 35: 1704–1706. doi: 10.1002/anie.199617041

Author Information

  1. Department of Chemistry Iowa State University, Ames, IA 50011 (USA) Fax: Int. code +(515) 294-5718

*Department of Chemistry Iowa State University, Ames, IA 50011 (USA) Fax: Int. code +(515) 294-5718

  1. †

    Dedicated to Professor Hans Georg von Schnering on the occasion of his 65th birthday

Publication History

  1. Issue published online: 22 DEC 2003
  2. Article first published online: 22 DEC 2003
  3. Manuscript Received: 22 FEB 1996

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Keywords:

  • clusters;
  • rare earth metal compounds;
  • solid-state structures
Thumbnail image of graphical abstract

A missing link in the chemistry of rare earth metal cluster compounds stabilized by interstitial transition metals is the new La10Co2 dimeric cluster shown on the right with its iodine environment. The most remarkable structural features of this cluster are the two edge-sharing La octahedra, each centered by a Co atom.

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