Communication

Palladium-Catalyzed Regioselective Mono- and Diarylation Reactions of 2-Phenylphenols and Naphthols with Aryl Halides†

  1. Tetsuya Satoh,
  2. Yuichiro Kawamura,
  3. Prof. Dr. Masahiro Miura*,
  4. Prof. Dr. Masakatsu Nomura

Article first published online: 22 DEC 2003

DOI: 10.1002/anie.199717401

Issue

Angewandte Chemie International Edition in English

Angewandte Chemie International Edition in English

Volume 36, Issue 16, pages 1740–1742, September 1, 1997

Additional Information

How to Cite

Satoh, T., Kawamura, Y., Miura, M. and Nomura, M. (1997), Palladium-Catalyzed Regioselective Mono- and Diarylation Reactions of 2-Phenylphenols and Naphthols with Aryl Halides. Angewandte Chemie International Edition in English, 36: 1740–1742. doi: 10.1002/anie.199717401

Author Information

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565 (Japan), Fax: Int. code + (6) 879-7362, e-mail: miura@ap.chem.eng.osaka-u.ac.jp.

*Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565 (Japan), Fax: Int. code + (6) 879-7362, e-mail: miura@ap.chem.eng.osaka-u.ac.jp.

  1. †

    We think Ms. Y. Miyaji of the Instrumental Analysis Center, Osaka University, for helpful assistance in obtaining NMR spectra.

Publication History

  1. Issue published online: 22 DEC 2003
  2. Article first published online: 22 DEC 2003
  3. Manuscript Received: 4 MAR 1997

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Keywords:

  • biaryls;
  • C[BOND]C coupling;
  • homogeneous catalysis;
  • O ligands;
  • palladium

Graphical Abstract

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Not only monoarylation but also diarylation of 2-phenylphenols with aryl iodides proceeds effectively and regioselectively when a palladium catalyst and an appropriate base are employed. The products are 1,2-diphenyl- and 1,2,3-triphenylbenzene derivatives, respectively (see below). Also discussed is the arylation of 1- and 2-naphthols. X = H, OMe; Y = H, Me; Z = H, OMe, NO2.

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