C.M.K. thanks the NSERC (Canada) for a postdoctoral fellowship.
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Revelations in Dinitrogen Activation and Functionalization by Metal Complexes†
Article first published online: 25 FEB 2004
DOI: 10.1002/anie.200301712
Copyright © 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Angewandte Chemie International Edition
Volume 43, Issue 10, pages 1186–1189, February 27, 2004
Additional Information
How to Cite
Kozak, C. M. and Mountford, P. (2004), Revelations in Dinitrogen Activation and Functionalization by Metal Complexes. Angew. Chem. Int. Ed., 43: 1186–1189. doi: 10.1002/anie.200301712
- †
Publication History
- Issue published online: 25 FEB 2004
- Article first published online: 25 FEB 2004
- Abstract
- Article
- References
- Cited By
Keywords:
- coordination modes;
- enzyme catalysis;
- molybdenum;
- nitrogen fixation;
- nitrogenases
A monumental achievement for coordination chemistry that also re-addresses the role of molybdenum in the nitrogenase FeMo cofactor is the discovery of the catalytic reduction of dinitrogen at a well-defined molybdenum complex by protons and electrons (see picture).