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Keywords:

  • cycloaddition;
  • epoxyquinoids;
  • natural products;
  • total synthesis
Thumbnail image of graphical abstract

The [4+2] dimerization of epoxyquinol 1 is rendered irreversible by formation of a hemiacetal in the enantioselective total synthesis of the ubiquitin-activating enzyme inhibitor (+)-panepophenanthrin (2).