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Keywords:

  • alkynes;
  • cross-coupling;
  • macrocycles;
  • metathesis;
  • natural products
Thumbnail image of graphical abstract

The highly selective actin-binding latrunculins (e.g. 1) play a prominent role as probe molecules in chemical biology. A highly concise, productive, and inherently flexible approach to 1 illustrates the excellent profile and use of metal-catalyzed C[BOND]C bond formations.