Communication

Bispidine Ligand Effects on Iron/Hydrogen Peroxide Chemistry†

  1. Michael R. Bukowski2,
  2. Peter Comba Prof Dr.1,
  3. Christian Limberg Prof. Dr.3,
  4. Michael Merz Dr.1,
  5. Lawrence Que Jr. Prof. Dr.2,
  6. Tobias Wistuba Dr.1

Article first published online: 25 FEB 2004

DOI: 10.1002/anie.200352523

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 43, Issue 10, pages 1283–1287, February 27, 2004

Additional Information

How to Cite

Bukowski, M. R., Comba, P., Limberg, C., Merz, M., Que, L. and Wistuba, T. (2004), Bispidine Ligand Effects on Iron/Hydrogen Peroxide Chemistry. Angew. Chem. Int. Ed., 43: 1283–1287. doi: 10.1002/anie.200352523

Author Information

  1. 1

    Universität Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany, Fax: (+49) 6226-546617

  2. 2

    Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis MN 55455, USA, Fax: (+1) 612-624-7029

  3. 3

    Humboldt-Universität zu Berlin, Institut für Chemie, Brook-Taylor-Strasse 2, 12489 Berlin, Germany, Fax: (+49) 30-2093-6966

  1. †

    Financial support by the German Science Foundation (DFG to P.C. and C.L.) and the U.S. National Institutes of Health (GM-33162 to L.Q.) are gratefully acknowledged.

Publication History

  1. Issue published online: 25 FEB 2004
  2. Article first published online: 25 FEB 2004
  3. Manuscript Received: 31 JUL 2003

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Keywords:

  • coordination modes;
  • iron;
  • ligands;
  • stereochemistry
Thumbnail image of graphical abstract

. ‥and yet so different. Non-heme iron complexes catalyze the stereoselective oxidation of C[BOND]H and C[DOUBLE BOND]C bonds. Isomeric FeIII-η1-hydroperoxo and FeIII-η2-peroxo complexes (see picture), important intermediates in these reactions, were studied by EPR, resonance Raman, and UV/Vis spectroscopies.

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