This work was financially supported by Ministry of Science and Technology of China (G2000048010) and National Natural Science Foundation of China (20133030, 20332030).
Pd Nanoparticles Immobilized on Molecular Sieves by Ionic Liquids: Heterogeneous Catalysts for Solvent-Free Hydrogenation†
Article first published online: 2 MAR 2004
Copyright © 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 43, Issue 11, pages 1397–1399, March 5, 2004
How to Cite
Huang, J., Jiang, T., Gao, H., Han, B., Liu, Z., Wu, W., Chang, Y. and Zhao, G. (2004), Pd Nanoparticles Immobilized on Molecular Sieves by Ionic Liquids: Heterogeneous Catalysts for Solvent-Free Hydrogenation. Angew. Chem. Int. Ed., 43: 1397–1399. doi: 10.1002/anie.200352682
- Issue published online: 2 MAR 2004
- Article first published online: 2 MAR 2004
- Manuscript Revised: 29 DEC 2003
- Manuscript Received: 20 AUG 2003
- heterogeneous catalysis;
- ionic liquids;
A three-piece suite: The immobilization of a Pd-nanoparticle catalyst onto the surface of a molecular sieve by an ionic liquid (1,1,3,3-tetramethylguanidinium lactate) has been accomplished (see TEM image). The nanoparticle/ionic liquid/molecular sieve combination exhibits excellent synergistic effects that enhance the activity and durability of the catalyst for the hydrogenation of olefins.