We gratefully acknowledge financial support from the Air Force Office of Scientific Research through F49620-00-1-0103 and the Army Research Office through MURI DAAD19-99-1-0316. Instrumentation for this research was partially funded by NSF grand DGE-0114443. The authors would like to thank Prof. John R. Reynolds at University of Florida for helpful discussions. We thank Dr. Hieu Duong and Ryan Chiechi for recording the video display of color switching.
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A Red, Green, and Blue (RGB) Polymeric Electrochromic Device (PECD): The Dawning of the PECD Era†
Article first published online: 27 JAN 2004
DOI: 10.1002/anie.200352910
Copyright © 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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How to Cite
Sonmez, G., Shen, C. K. F., Rubin, Y. and Wudl, F. (2004), A Red, Green, and Blue (RGB) Polymeric Electrochromic Device (PECD): The Dawning of the PECD Era. Angew. Chem. Int. Ed., 43: 1498–1502. doi: 10.1002/anie.200352910
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Publication History
- Issue published online: 9 MAR 2004
- Article first published online: 27 JAN 2004
- Manuscript Received: 18 SEP 2003
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- 35Since PDDTP was insoluble in any solvent, an alkyl-substituted counterpart of the monomer (Supporting Information; Figure S2) was synthesized and electrochemically polymerized under the same conditions. Then polymer films were reduced electrochemically in monomer-free electrolyte solution and dissolved in [D2]tetrachloroethane. 13C NMR spectroscopy of the resulting polymer demonstrated that hydrogen atoms on the α and α′ positions of the thiophene rings labeled with the letters c and d (Supporting Information) remained after electrochemical polymerization confirming the proposed structure for PDDTP. The related work for alkyl-substituted PDDTP will be published separately.
- 36A device made by using initials of “Exotic Materials Institute” is also available, Figure S8 of Supporting Information.
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