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Keywords:

  • antimony;
  • electronic structure;
  • hafnium;
  • solid-state structures

Graphical Abstract

Thumbnail image of graphical abstract

T time: The new binary antimonide Hf5Sb9 forms a unique variant of a square-planar net, namely an unprecedented yet simple T-shaped net (see picture, green) formed by antimony atoms (red). The electronic structure and bonding in the solid state are analyzed by theoretical methods.