We are grateful for financial support from the Swedish Research Council, the Swedish Foundation for Strategic Research, and the Ministerio de Educación y Ciencia of Spain.
1521-3773/asset/2002_left.gif?v=1&s=ac6b0d94a94d7ce7a210002b8096b42feffc0bcf)
1521-3773/asset/2002_right.gif?v=1&s=451042aa3415ae3ad0729984d26dee1866aca82e)
Communication
You have free access to this content
Highly Compatible Metal and Enzyme Catalysts for Efficient Dynamic Kinetic Resolution of Alcohols at Ambient Temperature†
Article first published online: 1 DEC 2004
DOI: 10.1002/anie.200461416
Copyright © 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Martín-Matute, B., Edin, M., Bogár, K. and Bäckvall, J.-E. (2004), Highly Compatible Metal and Enzyme Catalysts for Efficient Dynamic Kinetic Resolution of Alcohols at Ambient Temperature. Angew. Chem. Int. Ed., 43: 6535–6539. doi: 10.1002/anie.200461416
- †
Publication History
- Issue published online: 1 DEC 2004
- Article first published online: 1 DEC 2004
- Manuscript Received: 23 JUL 2004
Cited in:
- CrossRef
This article has been cited by:
- 1, , , Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes, Dalton Transactions, 2012, 41, 6, 1660
- 2, , , BulkyN-Heterocyclic Carbene IPr* in Selected Organo- and Transition Metal-Mediated Catalytic Applications, Organometallics, 2012, 120326073114000
- 3, , , Efficient dynamic kinetic resolution of racemic secondary alcohols by a chemoenzymatic system using bifunctional iridium complexes with C–N chelate amido ligands, Chemical Communications, 2012, 48, 30, 3635
- 4, , , Chemoenzymatic dynamic kinetic resolution as a key step in the enantioselective synthesis of (S)-salbutamol, Collection of Czechoslovak Chemical Communications, 2011, 76, 7, 919
- 5, , , , , , , , Covalent anchoring of a racemization catalyst to CALB-beads: towards dual immobilization of DKR catalysts, Tetrahedron Letters, 2011, 52, 14, 1601
- 6, Development of Environmentally Benign Transformations via 1,3-Transposition of Hydroxyl Group, YAKUGAKU ZASSHI, 2011, 131, 10, 1453
- You have free access to this content7, , , Dynamic Kinetic Resolution of Amines and Amino Acids by Enzyme–Metal Cocatalysis, ChemCatChem, 2011, 3, 2Direct Link:
- 8, , , , , Enabling Industrial Biocatalytic Processes by Application of Silicone-Coated Enzyme Preparations, Advanced Synthesis & Catalysis, 2011, 353, 13Direct Link:
- 9, , , , , Enzymatic Racemization of Amines Catalyzed by Enantiocomplementary ω-Transaminases, Chemistry - A European Journal, 2011, 17, 1Direct Link:
- 10, , , , Penta-arylcyclopentadienyl complexes, Coordination Chemistry Reviews, 2011, 255, 15-16, 1733
- 11, , , , Racemization of secondary alcohols catalyzed by ruthenium: application to chemoenzymatic dynamic resolution, Tetrahedron: Asymmetry, 2011, 22, 18-19, 1790
- 12, , , , Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols, Organometallics, 2011, 30, 23, 6347
- 13, , , , , Ruthenium-Catalysed Epimerisation of Carbohydrate Alcohols as a Method to Determine the Equilibria for Epimer Interconversion in Hexopyranosides, European Journal of Organic Chemistry, 2011, 2011, 23Direct Link:
- 14, , , , Substituent Effect on Catalytic Activities of [{η5-Ar4C4COC(
![[DOUBLE BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8fe.gif)
O)Ar}Ru(CO)2Cl] in Racemization and DKR of Secondary Alcohols, ChemCatChem, 2011, 3, 2Direct Link: - 15, , , , , , BVMO-catalysed dynamic kinetic resolution of racemic benzyl ketones in the presence of anion exchange resins, Organic & Biomolecular Chemistry, 2010, 8, 5, 1121
- 16, , , , Chemoenzymatic Dynamic Kinetic Resolution of Alcohols and Amines, European Journal of Organic Chemistry, 2010, 2010, 6Direct Link:
- 17, , , Chemoenzymatic Dynamic Kinetic Resolution of Axially Chiral Allenes, Chemistry - A European Journal, 2010, 16, 15Direct Link:
- 18, , , Fast racemization and dynamic kinetic resolution of primary benzyl amines, Tetrahedron Letters, 2010, 51, 42, 5581
- 19, , , , Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes, Journal of the American Chemical Society, 2010, 132, 38, 13146
- 20, , , Ruthenium Pincer-Catalyzed Acylation of Alcohols Using Esters with Liberation of Hydrogen under Neutral Conditions, Advanced Synthesis & Catalysis, 2010, 352, 18Direct Link:
- 21, , , , Chemoenzymatic and microbial dynamic kinetic resolutions, Chirality, 2009, 21, 4Direct Link:
- 22, , , , , CO Assistance in Ligand Exchange of a Ruthenium Racemization Catalyst: Identification of an Acyl Intermediate, Journal of the American Chemical Society, 2009, 131, 27, 9500
- 23, , , Racemization of Alcohols Catalyzed by [RuCl(CO)2(η5-pentaphenylcyclopentadienyl)]—Mechanistic Insights from Theoretical Modeling, Chemistry - A European Journal, 2009, 15, 21Direct Link:
- 24, , , , Ruthenium and enzyme-catalyzed dynamic kinetic resolution of alcohols, Comptes Rendus Chimie, 2009, 12, 9, 951
- 25, , , Unexpected Formation of a Cyclopentadienylruthenium Alkoxycarbonyl Complex with a Coordinated Câ•C Bond, Journal of the American Chemical Society, 2009, 131, 38, 13622
- 26, , An unexpected ruthenium complex and its unique behavior as catalyst in dynamic kinetic resolution of secondary alcohols, Chemical Communications, 2008, 42, 5333
- 27, , , Efficient Synthesis of β-Hydroxy Ketones from Allylic Alcohols by Catalytic Formation of Ruthenium Enolates, Chemistry - A European Journal, 2008, 14, 34Direct Link:
- 28, , , , , Highly efficient one pot dynamic kinetic resolution of benzoins with entrapped Pseudomonas stutzeri lipase, Journal of Molecular Catalysis B: Enzymatic, 2008, 52-53, 133
- 29, , , Modular Chemoenzymatic One-Pot Syntheses in Aqueous Media: Combination of a Palladium-Catalyzed Cross-Coupling with an Asymmetric Biotransformation, Angewandte Chemie International Edition, 2008, 47, 49Direct Link:
- 30, , , Modulare chemoenzymatische Eintopfsynthesen im wässrigen Medium: Kombination einer Palladium-katalysierten Kreuzkupplung mit einer asymmetrischen Biotransformation, Angewandte Chemie, 2008, 120, 49Direct Link:
- 31, , , , Racemization catalysts for the dynamic kinetic resolution of alcohols and amines, Coordination Chemistry Reviews, 2008, 252, 5-7, 647
- 32(S)-Selective Dynamic Kinetic Resolution of Allylic Alcohols by Enzyme-Metal Bicatalysis, Bulletin of the Korean Chemical Society, 2007, 28, 11, 2096
- 33, , , , , A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands, Chemical Communications, 2007, 18, 1837
- 34, , , , , Al(OTf)3 as a highly efficient catalyst for the rapid acetylation of alcohols, phenols and thiophenols under solvent-free conditions, Tetrahedron Letters, 2007, 48, 22, 3813
- 35, , , Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis, Organic & Biomolecular Chemistry, 2007, 5, 22, 3571
- 36, , Dynamic kinetic resolution catalyzed by enzymes and metals, Current Opinion in Chemical Biology, 2007, 11, 2, 226
- 37, , , , , , , Emulation of Racemase Activity by Employing a Pair of Stereocomplementary Biocatalysts, Chemistry - A European Journal, 2007, 13, 29Direct Link:
- 38, , , , Fast DKR of Amines Using Isopropyl 2-Methoxyacetate as Acyl Donor, European Journal of Organic Chemistry, 2007, 2007, 32Direct Link:
- 39, Guidelines and methodologies in asymmetric synthesis and catalysis, Comptes Rendus Chimie, 2007, 10, 3, 220
- 40, , , , Heterogeneous vanadium catalysts for racemization and chemoenzymatic dynamic kinetic resolution of benzylic alcohols, Green Chemistry, 2007, 9, 10, 1104
- 41, , High-yielding metalloenzymatic dynamic kinetic resolution of fluorinated aryl alcohols, Tetrahedron Letters, 2007, 48, 31, 5471
- 42, , , , , Iterative Tandem Catalysis of Secondary Diols and Diesters to Chiral Polyesters, Chemistry - A European Journal, 2007, 13, 29Direct Link:
- 43, , , , , Prediction of the Candida antarctica Lipase A Protein Structure by Comparative Modeling and Site-Directed Mutagenesis, ChemBioChem, 2007, 8, 12Direct Link:
- 44, , , , Racemization of Secondary Alcohols Catalyzed by Cyclopentadienylruthenium Complexes: Evidence for an Alkoxide Pathway by Fast β-Hydride Elimination–Readdition, Chemistry - A European Journal, 2007, 13, 21Direct Link:
- 45, , , , , , Relationship between structure, fluxionality and racemization activity in organometallic derivatives of polyoxometalates, Tetrahedron: Asymmetry, 2007, 18, 3, 367
- 46, , , , , Study of the Efficiency of Amino-Functionalized Ruthenium and Ruthenacycle Complexes as Racemization Catalysts in the Dynamic Kinetic Resolution of 1-Phenylethanol, Advanced Synthesis & Catalysis, 2007, 349, 17-18Direct Link:
- 47, , , , , (S)-Selective Kinetic Resolution and Chemoenzymatic Dynamic Kinetic Resolution of Secondary Alcohols, Chemistry - A European Journal, 2006, 12, 1Direct Link:
- 48, , Asymmetric transfer hydrogenation: chiral ligands and applications, Chemical Society Reviews, 2006, 35, 3, 226
- 49, , , , , Chiral Polyesters by Dynamic Kinetic Resolution Polymerization, Angewandte Chemie International Edition, 2006, 45, 13Direct Link:
- 50, , , , , , , Chiral polymers by iterative tandem catalysis, Chemical Communications, 2006, 30, 3169
- 51, , , , , Chirale Polyester durch dynamische kinetische Racematspaltungspolymerisation, Angewandte Chemie, 2006, 118, 13Direct Link:
- 52, , , Dynamic Kinetic Resolution over Cinchona-Modified Platinum Catalyst: Hydrogenation of Racemic Ethyl 2-Fluoroacetoacetate, Advanced Synthesis & Catalysis, 2006, 348, 4-5Direct Link:
- 53, , , , , Efficient dynamic kinetic resolution of secondary alcohols with a novel tetrafluorosuccinato ruthenium complex, Tetrahedron: Asymmetry, 2006, 17, 15, 2299
- 54, , , Highly Efficient Synthesis of Enantiopure Diacetylated C2-Symmetric Diols by Ruthenium- and Enzyme-Catalyzed Dynamic Kinetic Asymmetric Transformation (DYKAT), Chemistry - A European Journal, 2006, 12, 23Direct Link:
- 55, , , Lipase/Aluminium-katalysierte dynamische kinetische Racematspaltung von sekundären Alkoholen, Angewandte Chemie, 2006, 118, 39Direct Link:
- 56, , , Lipase/Aluminum-Catalyzed Dynamic Kinetic Resolution of Secondary Alcohols, Angewandte Chemie International Edition, 2006, 45, 39Direct Link:
- 57, , , , Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions, Chemical Society Reviews, 2006, 35, 3, 237
- 58, , Molecular iodine in isopropenyl acetate (IPA): a highly efficient catalyst for the acetylation of alcohols, amines and phenols under solvent free conditions, Tetrahedron Letters, 2006, 47, 30, 5345
- 59, , , Ruthenium- and lipase-catalyzed DYKAT of 1,2-diols: an enantioselective synthesis of syn-1,2-diacetates, Tetrahedron: Asymmetry, 2006, 17, 4, 708
- 60
- 61, , , , , Air-Stable Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols at Room Temperature, Organic Letters, 2005, 7, 20, 4523
- 62, , , , An S-Selective Lipase Was Created by Rational Redesign and the Enantioselectivity Increased with Temperature, Angewandte Chemie International Edition, 2005, 44, 29Direct Link:
- 63, , , , An S-Selective Lipase Was Created by Rational Redesign and the Enantioselectivity Increased with Temperature, Angewandte Chemie, 2005, 117, 29Direct Link:
- 64Dynamic Kinetic Resolutions and Asymmetric Transformations by Enzyme-Metal Combo Catalysis, Bulletin of the Korean Chemical Society, 2005, 26, 4, 515
- 65, , , , Highly Compatible Metal and Enzyme Catalysts for Efficient Dynamic Kinetic Resolution of Alcohols at Ambient Temperature., ChemInform, 2005, 36, 16Direct Link:
- 66, , , , , Highly Efficient Redox Isomerization of Allylic Alcohols at Ambient Temperature Catalyzed by Novel Ruthenium–Cyclopentadienyl Complexes—New Insight into the Mechanism, Chemistry - A European Journal, 2005, 11, 20Direct Link:
- 67, , , Removal of the acyl donor residue allows the use of simple alkyl esters as acyl donors for the dynamic kinetic resolution of secondary alcohols, Tetrahedron: Asymmetry, 2005, 16, 9, 1603
- 68, , 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), e-EROS Encyclopedia of Reagents for Organic Synthesis,Direct Link:
- 69, Enzyme Catalysis in the Synthesis of Active Pharmaceutical Ingredients,Direct Link:
- 70, , Lipases, e-EROS Encyclopedia of Reagents for Organic Synthesis,Direct Link:
- 71, , Lipases, e-EROS Encyclopedia of Reagents for Organic Synthesis,Direct Link: