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Highly Enantioselective Thiourea-Catalyzed Nitro-Mannich Reactions

Authors

Errata

This article is corrected by:

  1. Errata: Highly Enantioselective Thiourea-Catalyzed Nitro-Mannich Reactions Volume 44, Issue 45, 7327, Article first published online: 16 November 2005

  • This work was supported by the NIH through GM-43214, P50 GM069721, and a postdoctoral fellowship to T.P.Y.

Abstract

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Approaching “privileged” status? A new and highly effective enantioselective catalyst for the nitro-Mannich reaction was identified by modification of thiourea-based Strecker catalysts (see scheme). Products are obtained in high enantiomeric purity and up to 16:1 diastereoselectivity.

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