Communication

Modular Diamino- and Dioxophosphine Oxides and Chlorides as Ligands for Transition-Metal-Catalyzed C[BOND]C and C[BOND]N Couplings with Aryl Chlorides†

  1. Lutz Ackermann Dr.,
  2. Robert Born

Article first published online: 16 MAR 2005

DOI: 10.1002/anie.200462371

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 44, Issue 16, pages 2444–2447, April 15, 2005

Additional Information

How to Cite

Ackermann, L. and Born, R. (2005), Modular Diamino- and Dioxophosphine Oxides and Chlorides as Ligands for Transition-Metal-Catalyzed C[BOND]C and C[BOND]N Couplings with Aryl Chlorides. Angewandte Chemie International Edition, 44: 2444–2447. doi: 10.1002/anie.200462371

Author Information

  1. Ludwig-Maximilians-Universität München, Department Chemie und Biochemie, Butenandtstrasse 5–13, Haus F, 81377 München, Germany, Fax: (+49) 89-2180-77425

  1. †

    We thank Prof. Paul Knochel, the DFG (Emmy Noether-Programm), and the Ludwig-Maximilians-Universität for support.

Publication History

  1. Issue published online: 13 APR 2005
  2. Article first published online: 16 MAR 2005
  3. Manuscript Received: 20 OCT 2004

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Keywords:

  • cross-coupling;
  • nickel;
  • P ligands;
  • palladium;
  • phosphorus trichloride

Graphical Abstract

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Air-stable diamino- and dioxophosphine oxides were used as ligands in palladium-catalyzed Suzuki reactions of aryl chlorides. Additionally, a diaminophosphine chloride was applied to palladium- and nickel-catalyzed C[BOND]C and C[BOND]N bond-forming reactions.

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