The authors acknowledge the assistance of C. Day and J. Folmer. This work was supported by the ACS Petroleum Research Fund (#40963-G10) and the NCSU Faculty Research and Professional Development Fund.
1521-3773/asset/2002_left.gif?v=1&s=ac6b0d94a94d7ce7a210002b8096b42feffc0bcf)
1521-3773/asset/2002_right.gif?v=1&s=451042aa3415ae3ad0729984d26dee1866aca82e)
Communication
Pillared Hybrid Solids with Access to Coordinatively Unsaturated Metal Sites: An Alternative Strategy†
Article first published online: 16 MAR 2005
DOI: 10.1002/anie.200462715
Copyright © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Maggard, P. A., Yan, B. and Luo, J. (2005), Pillared Hybrid Solids with Access to Coordinatively Unsaturated Metal Sites: An Alternative Strategy. Angew. Chem. Int. Ed., 44: 2553–2556. doi: 10.1002/anie.200462715
- †
Publication History
- Issue published online: 21 APR 2005
- Article first published online: 16 MAR 2005
- Manuscript Received: 24 NOV 2004
- Abstract
- Article
- References
- Cited By
Keywords:
- cobalt;
- hydrothermal synthesis;
- microporous materials;
- nickel;
- solid-state structures
A layered effect: Replacement of pyrazine (A) with Co- or Ni-coordinated 2-pyrazinecarboxylate (pzc; B) between neutral AgReO4 layers (red and blue polyhedra) yields M(pzc)2(H2O)2AgReO4 (M=Co (shown) or Ni). This novel strategy is aimed at pillared solids with coordinated H2O that can be reversibly removed without causing structural collapse to give coordinatively unsaturated Ni and Co sites.