Communication

The Internuclear Potential, Electronic Structure, and Chemical Bond of Tellurium Selenide†

  1. Deike Banser Dr.1,
  2. Melanie Schnell Dr.1,
  3. Jens-Uwe Grabow Priv.-Doz. Dr.1,
  4. Emilio J. Cocinero2,
  5. Alberto Lesarri Prof. Dr.2,
  6. José L. Alonso Prof. Dr.2

Article first published online: 16 SEP 2005

DOI: 10.1002/anie.200501658

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 44, Issue 39, pages 6311–6315, October 7, 2005

Additional Information

How to Cite

Banser, D., Schnell, M., Grabow, J.-U., Cocinero, E. J., Lesarri, A. and Alonso, J. L. (2005), The Internuclear Potential, Electronic Structure, and Chemical Bond of Tellurium Selenide. Angew. Chem. Int. Ed., 44: 6311–6315. doi: 10.1002/anie.200501658

Author Information

  1. 1

    Institut für Physikalische Chemie, Lehrgebiet A, Universität Hannover, Callinstrasse 3–3A, 30167 Hannover, Germany, Fax: (+49) 511-7624009

  2. 2

    Grupo Espectroscopía Molecular (GES), Departamento de Química Física y Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena, s/n, 47005 Valladolid, Spain

  1. †

    We would like to thank the Deutscher Akademischer Austauschdienst (PPP D/0246239) as well as the Spanish ministry of education (Acciones Integradas HA-2002-0014) for funding a bilateral exchange program. M.S. thanks the Fonds der Chemischen Industrie (FCI) for support. J.-U.G. thanks the Deutsche Forschungsgemeinschaft (DFG) and th eLand Niedersachsen, A.L. and J.L.A. thank the Spanish Ministry of Science and Technology (BQU2003-03275). We are indepted to R. LeRoy, Waterloo, and S. Cooke, Vancouver, for fruitful discussions.

Publication History

  1. Issue published online: 30 SEP 2005
  2. Article first published online: 16 SEP 2005
  3. Manuscript Received: 13 MAY 2005

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Keywords:

  • Born–Oppenheimer breakdown;
  • chalcogens;
  • laser ablation;
  • rotational spectroscopy;
  • supersonic jets
Thumbnail image of graphical abstract

Joining the jet set: High-resolution, pure rotational spectra are obtained from a supersonic jet of TeSe prepared by laser ablation. The spectra give access to the internuclear potential, electronic structure (see picture), and details of the chemical bond of the first intermetallic 3Σ compound observed by microwave spectroscopy.

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