Communication

Diamido Rhodates(1−)†

  1. Pascal Maire Dr.,
  2. Frank Breher Dr.,
  3. Hansjörg Grützmacher Prof. Dr.

Article first published online: 20 SEP 2005

DOI: 10.1002/anie.200502036

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 44, Issue 39, pages 6325–6329, October 7, 2005

Additional Information

How to Cite

Maire, P., Breher, F. and Grützmacher, H. (2005), Diamido Rhodates(1−). Angew. Chem. Int. Ed., 44: 6325–6329. doi: 10.1002/anie.200502036

Author Information

  1. Department of Chemistry and Applied Biosciences, ETH-Hönggerberg, 8093 Zürich, Switzerland, Fax: (+41) 44-633-1032

  1. †

    This work was supported by the LANXESS AG and the Swiss National Science Foundation.

Publication History

  1. Issue published online: 30 SEP 2005
  2. Article first published online: 20 SEP 2005
  3. Manuscript Received: 13 JUN 2005

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Keywords:

  • alkene ligands;
  • amides;
  • binding models;
  • redox chemistry;
  • rhodium
Thumbnail image of graphical abstract

The filled/filled repulsion model can be used to explain qualitatively the trends in the acidity of the coordinated NH groups, the redox potentials of the amides, and the UV/Vis absorptions in different aggregates between a counter cation, [M(solv)n]+, and the first stable diamido rhodate(1−) anion (see structure and space-filling model), which was synthesized by using the tetradentate diamino diolefin ligand (S,S)-trop2dpen.

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