This work was supported by the SRC/ERC program of MOST/KOSEF (R11-2000-070-05003-0).
Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols†
Article first published online: 5 OCT 2005
Copyright © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 44, Issue 42, pages 6913–6915, October 28, 2005
How to Cite
Kwon, M. S., Kim, N., Seo, S. H., Park, I. S., Cheedrala, R. K. and Park, J. (2005), Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols. Angew. Chem. Int. Ed., 44: 6913–6915. doi: 10.1002/anie.200502422
- Issue published online: 25 OCT 2005
- Article first published online: 5 OCT 2005
- Manuscript Received: 12 JUL 2005
- CC coupling;
- heterogeneous catalysis;
An air-stable, heterogeneous, and recyclable catalyst composed of palladium nanoparticles entrapped in aluminum hydroxide was applied to a highly selective α alkylation. A wide range of aliphatic and aromatic ketones and primary alcohols were coupled to prepare enones in an O2 atmosphere and ketones in an argon atmosphere (see scheme).