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Towards Polymer-Based Hydrogen Storage Materials: Engineering Ultramicroporous Cavities within Polymers of Intrinsic Microporosity^†

Neil B. McKeown Prof.¹,
Bader Gahnem Dr.¹,
Kadhum J. Msayib Dr.¹,
Peter M. Budd Dr.²,
Carin E. Tattershall Dr.²,
Khalid Mahmood Dr.²,
Siren Tan²,
David Book Dr.³,
Henrietta W. Langmi Dr.³,
Allan Walton Dr.³

Article first published online: 10 FEB 2006

DOI: 10.1002/anie.200504241

Issue

Angewandte Chemie International Edition

Volume 45, Issue 11, pages 1804–1807, March 6, 2006

Additional Information

How to Cite

McKeown, N. B., Gahnem, B., Msayib, K. J., Budd, P. M., Tattershall, C. E., Mahmood, K., Tan, S., Book, D., Langmi, H. W. and Walton, A. (2006), Towards Polymer-Based Hydrogen Storage Materials: Engineering Ultramicroporous Cavities within Polymers of Intrinsic Microporosity. Angew. Chem. Int. Ed., 45: 1804–1807. doi: 10.1002/anie.200504241

Author Information

¹
School of Chemistry, Cardiff University, Cardiff, CF10 3AT, UK, Fax: (+44) 29-2087-4030
²
Organic Materials Innovation Centre, School of Chemistry, University of Manchester, Manchester, M13 9PL, UK, Fax: (+44) 161-275-4273
³
Department of Metallurgy and Materials, School of Engineering, University of Birmingham, Birmingham, B15 2TT, UK

Email: Neil B. McKeown Prof. (mckeownnb@cardiff.ac.uk), Peter M. Budd Dr. (peter.budd@manchester.ac.uk)

^†
We thank the EPSRC and the Higher Education Commission of Pakistan (K.M.) for funding.

Publication History

Issue published online: 1 MAR 2006
Article first published online: 10 FEB 2006
Manuscript Received: 29 NOV 2005

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1
R. F. Service, Science 2004, 305, 958–961.
2
L. Schlapbach, A. Zuttel, Nature 2001, 414, 353–358.
3
3a
A. Zecchina, S. Bordiga, J. G. Vitillo, G. Ricchiardi, C. Lamberti, G. Spoto, M. Bjorgen, K. P. Lillerud, J. Am. Chem. Soc. 2005, 127, 6361–6366;
3b
C. O. Arean, M. R. Delgado, G. T. Palomino, M. T. Rubio, N. M. Tsyganenko, A. A. Tsyganenko, E. Garrone, Microporous Mesoporous Mater. 2005, 80, 247–252;
3c
H. W. Langmi, A. Walton, M. M. Al-Mamouri, S. R. Johnson, D. Book, J. D. Speight, P. P. Edwards, I. Gameson, P. A. Anderson, I. R. Harris, J. Alloys Compd. 2003, 356–357, 710–715.
4
4a
M. G. Nijkamp, J. Raaymakers, A. J. van Dillen, K. P. de Jong, Appl. Phys. A 2001, 72, 619–623;
4b
H. G. Schimmel, G. J. Kearley, M. G. Nijkamp, C. T. Visserl, K. P. de Jong, F. M. Mulder, Chem. Eur. J. 2003, 9, 4764–4770;
Direct Link:
4c
B. Panella, M. Hirscher, S. Roth, Carbon 2005, 43, 2209–2214.
5
J. L. C. Rowsell, A. R. Millward, K. S. Park, O. M. Yaghi, J. Am. Chem. Soc. 2004, 126, 5666–5667.
6
6a
N. L. Rosi, J. Eckert, M. Eddaoudi, D. T. Vodak, J. Kim, M. O'Keeffe, O. M. Yaghi, Science 2003, 300, 1127–1129;
6b
B. Panella, M. Hirscher, Adv. Mater. 2005, 17, 538–541.
Direct Link:
7
Y. Gogotsi, R. K. Dash, G. Yushin, T. Yildirim, G. Laudisio, J. E. Fischer, J. Am. Chem. Soc. 2005, 127, 16006–16007.
8
H. Chun, D. N. Dybtsev, H. Kim, K. Kim, Chem. Eur. J. 2005, 11, 3521–3529.
Direct Link:
9
O. Hubner, A. Gloss, M. Fichtner, W. Klopper, J. Phys. Chem. A 2004, 108, 3019–3023.
10
10a
P. M. Budd, B. S. Ghanem, S. Makhseed, N. B. McKeown, K. Msayib, C. E. Tattershall, Chem. Commun. 2004, 230–231;
10b
P. M. Budd, N. B. McKeown, D. Fritsch, J. Mater. Chem. 2005, 15, 1977–1986;
10c
N. B. McKeown, P. M. Budd, K. J. Msayib, B. S. Ghanem, H. J. Kingston, C. E. Tattershall, S. Makhseed, K. J. Reynolds, D. Fritsch, Chem. Eur. J. 2005, 11, 2610–2620;
Direct Link:
10d
N. B. McKeown, S. Hanif, K. Msayib, C. E. Tattershall, P. M. Budd, Chem. Commun. 2002, 2782–2783;
10e
N. B. McKeown, S. Makhseed, P. M. Budd, Chem. Commun. 2002, 2780–2781.
11
P. M. Budd, E. S. Elabas, B. S. Ghanem, S. Makhseed, N. B. McKeown, K. Msayib, C. E. Tattershall, D. Wang, Adv. Mater. 2004, 16, 456–459.
Direct Link:
12
P. M. Budd, B. Ghanem, K. Msayib, N. B. McKeown, C. Tattershall, J. Mater. Chem. 2003, 13, 2721–2726.
13
P. M. Budd, K. J. Msayib, C. E. Tattershall, B. S. Ghanem, K. J. Reynolds, N. B. McKeown, D. Fritsch, J. Membr. Sci. 2005, 251, 263–269.
14
It is notable that one of the pioneering groups in the MOF area has recently reported ordered “covalent organic frameworks” (COFs) with the aim of enhancing gravimetric hydrogen capacity, see A. P. Coté, A. I. Benin, N. W. Ockwig, M. O'Keeffe, A. J. Matzger, O. M. Yaghi, Science 2005, 310, 1166–1170.
15
A. S. Lindsay, J. Chem. Soc. 1965, 1685–1692.
- CrossRef,
- Web of Science® Times Cited: 109
16
G. Horvath, K. Kawazoe, J. Chem. Eng. Jpn. 1983, 16, 470–475.
17
By IUPAC definition, pores of dimensions less than 2 nm are micropores (see D. H. Everett, Pure Appl. Chem. 1972, 44, 577–638), however, micropores are increasing subdivided into ultramicropores (less than 0.7 nm) and supermicropores 0.7–2.0 nm (see
- CrossRef
J. Rouquerol, F. Rouquerol, K. S. W. Sing, Adsorption by Powders and Porous Solids, Academic Press, London, 1999).
18
A. Anson, M. Benham, J. Jagiello, M. A. Callejas, A. M. Benito, W. K. Maser, A. Zuttel, P. Sudan, M. T. Martinez, Nanotechnology 2004, 15, 1503–1508.
19
19a
K. W. Chapman, P. D. Southon, C. L. Weeks, C. J. Kepert, Chem. Commun. 2005, 3322–3324;
19b
B. L. Chen, N. W. Ockwig, A. R. Millward, D. S. Contreras, O. M. Yaghi, Angew. Chem. 2005, 117, 4823–4827;
Direct Link:
Angew. Chem. Int. Ed. 2005, 44, 4745–4749;
Direct Link:
19c
M. Dinca, J. R. Long, J. Am. Chem. Soc. 2005, 127, 9376–9377;
19d
L. Pan, M. B. Sander, X. Y. Huang, J. Li, M. Smith, E. Bittner, B. Bockrath, J. K. Johnson, J. Am. Chem. Soc. 2004, 126, 1308–1309.
20
Y. Tsujita, Prog. Polym. Sci. 2003, 28, 1377–1401.
21
Basic Research Needs for the Hydrogen Economy, Office of Basic Energy Sciences, US Department of Energy, 2004.

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Towards Polymer-Based Hydrogen Storage Materials: Engineering Ultramicroporous Cavities within Polymers of Intrinsic Microporosity^†

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Angewandte Chemie International Edition

How to Cite

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Publication History

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