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Keywords:

  • crystal growth;
  • metal–organic frameworks;
  • microporous materials;
  • polymers;
  • supramolecular chemistry
Thumbnail image of graphical abstract

Promoting diversity: Polymer-induced heteronucleation provides kinetic access to three new metal–organic frameworks derived from dicarboxylic acid linkers (see structures). This method is useful as a general approach for discovering extended solids with new topologies that are inaccessible by traditional methods.