Communication

Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101†

  1. Michel Latroche Dr.1,
  2. Suzy Surblé2,
  3. Christian Serre Dr.2,
  4. Caroline Mellot-Draznieks Dr.2,
  5. Philip L. Llewellyn Dr.3,
  6. Jin-Ho Lee4,
  7. Jong-San Chang Dr.4,
  8. Sung Hwa Jhung Dr.4,
  9. Gérard Férey Prof.2

Article first published online: 23 NOV 2006

DOI: 10.1002/anie.200600105

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 45, Issue 48, pages 8227–8231, December 11, 2006

Additional Information

How to Cite

Latroche, M., Surblé, S., Serre, C., Mellot-Draznieks, C., Llewellyn, P. L., Lee, J.-H., Chang, J.-S., Jhung, S. H. and Férey, G. (2006), Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101. Angewandte Chemie International Edition, 45: 8227–8231. doi: 10.1002/anie.200600105

Author Information

  1. 1

    Laboratoire de Chimie Métallurgique des Terres Rares, CNRS, UPR 209, 94320 Thiais Cedex, France, Fax: (+33) 149-781-203

  2. 2

    Institut Lavoisier, UMR 8180, Université de Versailles—St Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France

  3. 3

    MADIREL, UMR 6121, Université de Provence-CNRS, Centre de Saint Jérôme, 13397 Marseille Cedex 20, France

  4. 4

    Korea Research Institute of Chemical Technology, Jang-dong 100, Yuseong-Gu, 305-600 Daejon, South Korea

  1. †

    The authors are grateful to Dr. A. Vimont and Pr. M. Daturi (LCS, Caen, France) for the preliminary in situ IR experiments. J.-S.C. would like to thank KRICT for supporting this work under the institutional research program.

Publication History

  1. Issue published online: 4 DEC 2006
  2. Article first published online: 23 NOV 2006
  3. Manuscript Revised: 22 SEP 2006
  4. Manuscript Received: 10 JAN 2006

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Keywords:

  • carboxylate ligands;
  • chromium;
  • hydrogen;
  • mesoporous materials;
  • physisorption

Graphical Abstract

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Large hydrogen-storage capacity at liquid-nitrogen temperature is exhibited by the metal–organic framework MIL-101. In the zeotype architecture of this porous solid (see picture) each intersection of the cages is occupied by a supertetrahedron formed by trimers of chromium octahedra assembled with benzene-1,4-dicarboxylate ligands.

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