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Keywords:

  • boron;
  • charge transfer;
  • fluorescence;
  • fluorides;
  • sensors

Graphical Abstract

Thumbnail image of graphical abstract

A real turn-on: Two nonplanar three-coordinate boron compounds were synthesized as fluorescent sensors for fluoride that utilize charge-transfer emission. The fluorescence of one of the sensors turns on (see picture) and the other turns off in the presence of fluoride.