Communication

Phosphole-Modified Poly(thiophene)s: Unique Postfunctionalizable Conjugated Polymers That Sense Elemental Chalcogenides†

  1. Manuel Sebastian Dr.1,
  2. Muriel Hissler Dr.1,
  3. Claire Fave Dr.1,
  4. Joëlle Rault-Berthelot Dr.1,
  5. Christophe Odin Dr.2,
  6. Régis Réau Prof. Dr.1

Article first published online: 14 AUG 2006

DOI: 10.1002/anie.200601844

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 45, Issue 37, pages 6152–6155, September 18, 2006

Additional Information

How to Cite

Sebastian, M., Hissler, M., Fave, C., Rault-Berthelot, J., Odin, C. and Réau, R. (2006), Phosphole-Modified Poly(thiophene)s: Unique Postfunctionalizable Conjugated Polymers That Sense Elemental Chalcogenides. Angewandte Chemie International Edition, 45: 6152–6155. doi: 10.1002/anie.200601844

Author Information

  1. 1

    Sciences Chimiques de Rennes, CNRS UMR 6226 Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France, Fax: (+33) 2-2323-6939

  2. 2

    Groupe Matière Condensée et Matériaux, CNRS UMR 6626 Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France

  1. †

    We thank the Ministère de la Recherche, the Institut Universitaire de France, the CNRS, and the Deutsche Forschungsgemeinschaft.

Publication History

  1. Issue published online: 11 SEP 2006
  2. Article first published online: 14 AUG 2006
  3. Manuscript Received: 10 MAY 2006

Funded by

  • Ministère de la Recherche
  • Institut Universitaire de France
  • CNRS
  • Deutsche Forschungsgemeinschaft

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Keywords:

  • chalcogens;
  • cyclic voltammetry;
  • electropolymerization;
  • phosphorus heterocycles;
  • sensors

Graphical Abstract

Thumbnail image of graphical abstract

Bulk response: Following the development of conjugated polymers that sense ions or neutral molecules, the first π-conjugated polymer which is capable of detecting elemental chalcogens is presented. Individual reactions at the phosphole moieties (see picture) result in macroscopic responses of the bulk polymer.

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