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Keywords:

  • allylic alkylation;
  • asymmetric catalysis;
  • enols;
  • ketones;
  • palladium
Thumbnail image of graphical abstract

Triple A: Recent developments in palladium-catalyzed decarboxylative asymmetric allylic alkylation (AAA) reactions provide easy access to highly enantioenriched ketones with α-positioned quaternary or tertiary carbon stereocenters under mild conditions.