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Enantioselective Palladium-Catalyzed Decarboxylative Allylic Alkylations

Authors

  • Shu-Li You Prof. Dr.,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P.R. China, Fax: (+86) 21-5492-5087
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  • Li-Xin Dai Prof.

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P.R. China, Fax: (+86) 21-5492-5087
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  • We gratefully acknowledge the Chinese Academy of Sciences for generous financial support.

Abstract

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Triple A: Recent developments in palladium-catalyzed decarboxylative asymmetric allylic alkylation (AAA) reactions provide easy access to highly enantioenriched ketones with α-positioned quaternary or tertiary carbon stereocenters under mild conditions.

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