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Tsuji–Trost Allylic Alkylation with Ketone Enolates

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Abstract

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The traditional restriction of the palladium-catalyzed allylation to stabilized carbanions has been overcome. Recent studies reveal that preformed “hard” enolates can serve as nucleophiles, and routes to novel stereoselective variants of the Tsuji–Trost method have thus been opened.

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